新葡萄京官网8455

设为新葡萄京官网8455 |  中文 |  English

内容检索:

XML 地图 | Sitemap 地图

头像

蔡琥
教授
博士
有机化学
caihu@ncu.edu.cn
有机合成、分子基功能材料
 

 

1986.09 - 1990.06 兰州大学化学系有机化学专业,获学士学位

1990.06 - 1993.08 江西新余钢铁企业第一中心试验室,助理工程师

  1993.09 - 1996.06 南京大学化学化工学院有机化学专业, 获硕士学位

  1996.09 - 1999.06 南京大学化学化工学院无机化学专业, 获博士学位

  1999.06 - 2002.09 美国田纳西大学化学系博士后

  2002.10 - 2004.03 美国凯斯西储大学化学系副研究员

  2004.04 - 2007.05 美国堪萨斯大学化学系博士后

  2007.06 -至今 新葡萄京官网8455工作

教学概况

    绿色化学、有机化学、现代有机合成、金属有机化学

    主要从事绿色化学与机功能分子材料的精准合成及其在光电转换、传感以及信息存储技术上的应用等研究。包括研究探索有机分子中惰性碳氢键、碳碳键的选择性活化与官能团化方法,开发绿色高效的催化体系,实现有机功能分子的定向、精准合成;同时,立足于解决功能材料在分子结构设计与功能调控方面存在的关键科知识题与技术需求,结合现代分析传感探测技术,研究有机分子传感及影像、有机发光与信息存储等功能材料与器件的可控合成与性能的调控,以期实现有机功能材料在微电子、生物医药、信息与通讯等高新技术领域应用瓶颈的突破。已在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Commun., Org. Lett., Green Chem.等国内外重要学术刊物上已发表论文100余篇,授权发明专利多项。

    目前主持国家自然科学基金4项,参加国家科技部重点基础发展研究计划(973)一项。

   江西省侨联特聘专家,江西省化学化工学会常务理事,江西省欧美同学会·江西省留学人员联谊会常务理事

    

    1.  Rational design of ceramic-like molecular ferroelectric by quasi-spherical theory. Wei, Zhen-Hong; Jiang, Zhen-Tao; Zhang, Xiu-Xiu; Li, Ming-Li; Tang, Yuan-Yuan; Chen, Xiao-Gang; Cai, Hu*; Xiong, Ren-Gen*. Journal of the American Chemical Society, 2020, 142(4), 1995-2000.

    2.  Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides. Fu, Zhengjiang; Hao, Guangguo; Fu, Yaping; He, Dongdong; Tuo, Xun; Guo, Shengmei; Cai, Hu*. Organic Chemistry Frontiers 2020, 7(3), 590-595.

    3.  Pd-Catalyzed Decarboxylative Ortho-Halogenation of Aryl Carboxylic Acids with Sodium Halide NaX Using Carboxyl as a Traceless Directing Group. Fu, Zhengjiang; Jiang, Yongqing; Wang, Shuiliang; Song, Yuanyuan; Guo, Shengmei; Cai, Hu*. Organic Letters, 2019, 21(9), 3003-3007.

    4.  Nucleophile-controlled mono- and bis-phosphonation of amino-2-en-1-ones via catalyst-free C(sp3)-N bond cleavage. Huang, Ling; Zhang, Zhebin; Jie, Kun; Wang, Yufeng; Fu, Zhengjiang; Guo, Shengmei; Cai, Hu*. Organic Chemistry Frontiers 2018, 5(24), 3548-3552.

    5.  Narrowest Band Gap Ever Observed in Molecular Ferroelectrics: Hexane-1,6-diammonium Pentaiodobismuth(III). Zhang, Han-Yue; Wei, Zhenhong; Li, Peng-Fei; Tang, Yuan-Yuan; Liao, Wei-Qiang; Ye, Heng-Yun; Cai, Hu*; Xiong, Ren-Gen*; Angewandte Chemie, International Edition, 2018, 57(2), 526-530.

    6.  Metal-free phosphonation of benzoxazoles and benzothiazoles under oxidative conditions. Gong, Jiuhan; Huang, Ling; Deng, Qidu; Jie, Kun; Wang, Yufeng; Guo, Shengmei*; Cai, Hu*; Organic Chemistry Frontiers, 2017, 4(9), 1781-1784.

    7.  Selective phosphoramidation and phosphonation of benzoxazoles via sequence control. Huang, Ling; Gong, Jiuhan; Zhu, Zheng; Wang, Yufeng; Guo, Shengmei*; Cai, Hu*; Organic Letters, 2017, 19(9), 2242-2245.

    8.  Halogenation and Cyanation of Electron-Deficient Aryl Carboxylic Acids via Cu Mediator as Well as Electron-Rich Ones through Pd Catalyst under Aerobic Conditions, Fu, Zhengjiang; Li, Zhaojie; Song, Yuanyuan; Yang, Ruchun; Liu, Yanzhu; Cai, Hu*; Journal of Organic Chemistry, 2016, 81(7), 2794-2803.

    9.  Palladium-Catalyzed Decarboxylative Methylthiolation of Aromatic Carboxylic Acids by Using DMSO as the Sulfurizing Reagent. Fu, Zhengjiang; Li, Zhaojie; Xiong, Qiheng; Cai, Hu*. European Journal of Organic Chemistry, 2014, 2014(35), 7798-7802.

    10.  C-H Bond Activation during and after the Reactions of a Metallacyclic Amide with Silanes: Formation of a μ-Alkylidene Hydride Complex, Its H-D Exchange, and β-H Abstraction by a Hydride Ligand. Wang, Li; Hunter, Seth C.; Song, Zhimin; Steren, Carlos A.; Chen, Tianniu; Wei, Zhenhong; Cai, Hu*; Xue, Zi-Ling*. Chemistry - A European Journal, 2014, 20(20), 6033-6039.


 

XML 地图 | Sitemap 地图
XML 地图 | Sitemap 地图